by Garth W. Cane
Ethanol And Biodiesel Fuels (36-4)

Today, when we pull in to a gas station to refuel our RV, we often see stickers on the pump indicating that the fuel contains a percentage of ethanol or “biodiesel.” Here’s why this is the wave of the future.

W
ith the price of gasoline costing $1 per litre or more this year, RV’ers are considering shorter trips. Demand for gasoline is actually more prone to wild swings than demand for crude oil. This is because only a few countries have the ability to refine crude oil for use as gasoline. The refining process adds an extra layer of time and cost to gasoline inventories and production. The international perspective of the petroleum industry is very complex – for example, oil-producing countries like Iran, which pumps out more crude than 80% of the rest of the world’s producers, must re-import their own crude as gasoline because of limited refining capability.

The use of non-petroleum additives in the gasoline formulation has a number of advantages for the modern motorist. To better understand why RV’ers should take a serious look at the new blended fuels, you have to step back to discover how these fuels address your needs.

First of all, what are Ethanol and Biodiesel fuels?

Ethanol (which is also called ethyl alcohol or grain alcohol, is an alcohol-based alternative fuel that is blended with gasoline to produce a fuel with a higher octane rating and fewer harmful emissions than unblended gasoline. Ethanol is produced by fermenting and distilling grains such as corn, barley and wheat. Another form of ethanol, called bioethanol, can be made from many types of trees and grasses, although the process is more difficult.

Biodiesel is a clean burning alternative fuel produced from a variety of renewable agricultural resources, such as soybeans and canola, animal fats, and recycled cooking oils. It can be burned in any standard, unmodified diesel engine either in pure form (BD100) or, depending on outside air temperatures, in a blend of any proportion with petroleum diesel. The most popular types of vegetable oils used in biodiesel fuel are soybean and rapeseed oil.

While biodiesel is not regular vegetable oil and is not safe to swallow, it is biodegradable, so it is much less harmful to the environment if spilled. Biodiesel is made through a process called transesterification. This process makes vegetable oil and animal fat into esterified oil (which has the glycerin removed), which can be used as diesel fuel, or mixed with regular diesel fuel. The rising cost of soybean and other oils, which account for the bulk of biodiesel fuel stock, has led to the push to use cheap and plentiful animal fats. Tyson Foods has announced that it is partnering with Conoco to produce biodiesel fuel from chicken fats.

Biodiesel seamlessly integrates with current engine technology and fueling infrastructure. In fact, it is the first clean fuel that does not require fleet operators to purchase new vehicles or construct new facilities. Pure biodiesel is fully biodegradable, non-toxic to plants, animals and humans, and essentially free of sulphur and other aromatics. In Toronto, many street buses are running on biodiesel fuel stored in large tanks at the Toronto Transportation Commission (TTC). The use of this cleaner alternative to regular diesel fuel is growing throughout Canada. In places like Montreal, river ferries now operate on biodiesel fuel.

Gasoline blended with ethanol is also becoming more common throughout North America. One gallon of pure ethanol contains about 66 percent as much energy as a gallon of gasoline. A gallon of E85, a common blend of 85 percent ethanol and 15 percent gasoline, contains about 71 percent as much energy as a gallon of unblended gasoline. Drivers who use E85 can expect about 15 percent less fuel economy than they would get with gasoline. Other performance factors such as power, acceleration, and cruising speed are essentially equivalent in vehicles burning E85 and conventional fuels.

Most ethanol fuel sold at service stations today is a blend of 10% ethanol and 90% gasoline that sometimes is used to increase octane and improve emissions quality, but are not considered alternative fuels. When the percentage of ethanol increases to 20%, then modifications need to be made to the engine and fuel system. E85, a blend of 85 percent ethanol and 15 percent gasoline, is used in flexible fuel vehicles, which are offered by most major auto manufacturers. Flexible fuel vehicles can run on gasoline, E85, or any combination of the two. Although at this time, this fuel is not readily available at many service stations. My friend, Gary Sowerby, drove a General Motors E85 Yukon across Canada with cellulose ethanol fuel provided by Iogen.

A vehicle can not use a 20% blend without certain modifications to the fuel system. At the very least the fuel lines will need to be replaced since ethanol is corrosive and will degrade them from the inside to the point where fuel pressure will cause the line to rupture. Also, the electric fuel pumps will need to be modified to resist ethanol "dry rot".

A Canadian company, Iogen uses a process to produce ethanol from cellulose , the non-food portion of agricultural residues such as cereal straws and corn stalks. The lignin in the cellulose ethanol can be used to generate electricity to operate the production plant. Cellulose ethanol is a renewable, advanced biofuel that can be used in today’s cars. It is one of the most cost effective ways to reduce greenhouse gas emissions and gasoline use in road transport, and in this regard can deliver benefits similar to improved vehicle efficiency. Cellulose ethanol biorefineries will strengthen local economies by creating thousands of jobs, while making agriculture a more sustainable industry. Recent reports from the U.S. Department of Energy/Department of Agriculture state that there is enough biomass feedstock for cellulose ethanol production in the U.S. to displace approximately 40% of current U.S. gasoline consumption.

Dr. Jason Hill, of the University of Minnesota, said that “The environmental benefits of producing biofuels from diverse prairie biomass are striking. Producing and using ethanol from diverse prairie biomass can actually reduce the amount of carbon dioxide in the atmosphere. This is because a diverse prairie removes more carbon dioxide from the air and stores it in the soil. This, along with the nitrogen added to the soil by native legumes, actually restores fertility to degraded farmlands, and a prairie also provides wildlife habitat and reduces soil erosion and pollution of waterways with pesticides, herbicides and fertilizers”.

Ethanol production supports farmers and helps the economy, and because ethanol is produced domestically, from domestically grown crops, it reduces dependence on foreign oil and increases the nation’s energy independence. Many Canadian farmers that I have talked to about ethanol fuel express disappointment that Canadian fuel distributors who splash blend ethanol with regular gasoline are buying their corn stock from US farmers, who are subsidized by their government. I was told that UCO’s ethanol plant in Tiverton, in Western Ontario, buys corn from US farmers at $50 a ton less than Canadian farmers can grow it. It is then splash blended at the Sunoco refinery in London, ON. US federal corn subsidies totaled $37.3 billion last year. That's more than twice the amount spent on wheat subsidies, three times the amount spent on soybeans, and 70 times the amount spent on tobacco.

In the USA, President Bush has set high goals for the production of ethanol fuel from corn. This has helped push up the price of corn on the market with an increase in the cost of many food products that depend on corn. In Mexico, even the cost of tortillas has gone up. Since the farmer can make more money growing corn to be used to produce ethanol, he is not growing other crops, like wheat and grains. To produce the quantity of corn that Bush¡¯s goals call for, no other crop but corn could be grown by American farmers. So where will we get the food?

Adapting to Bio-Fuels

Modifications to most diesel engines are not needed when using the 20% or less blends of biodiesel fuel. If the engine was built since 1994, few if any changes will need to be made for running up to 100% biodiesel. Not many stations in Canada are offering biodiesel now, but it may be available in your area. Biodiesel shows a great deal of promise to help in solving some of our most pressing needs. Biodiesel fuel reduces smoke and soot in exhaust by 31%, carbon monoxide by 21% and hydrocarbons by 47% when used in a 20% blend with petroleum diesel fuel and a catalytic converter. If you can utilize biodiesel, do a little research and give biodiesel a chance.

Are there any problems with the new fuels? In the RV industry, we have found some fuel problems because of the way an RV is used. Since the alcohol in ethanol gasoline blends is hydroscopic (it absorbs water) and is heavier than the gasoline, in long term storage conditions, the alcohol tends to separate from the fuel and goes to the bottom of the tank next to the fuel pump. The RV engine was not designed to run on 100% alcohol. If the RV is being stored for the winter season, it is best to use up as much of the fuel as possible rather than topping the tank up as when we were using gasoline. When regular gasoline is used, we would top up the fuel tank before storage to prevent condensation in the tank.

When the vehicle first starts using ethanol blended fuel, more frequent fuel filter changes will be required as the ethanol cleans the fuel system of accumulated garbage. Ethanol is a corrosive fuel that can eat away at fuel lines from the inside out on older motorhomes and tow vehicles.

Algae can grow in biodiesel fuels as well as petro diesel. In warmer temperatures, this could be a problem. It is a dark slime that grows in the fuel tank and fuel lines. It may be necessary to use algicides to control the algae, especially in hot humid climates. Since the algae can block fuel filters, change the filters often.

In the wintertime, the wax component of diesel fuel that is used to increase the Cetane rating tends to clog the fuel filters. Anti-gel additives help to inhibit the formation of wax crystals, but they're not all created equal. Several companies have created formulas that work well with biodiesel fuel. One way to help prevent the wax crystals from clogging the filter is to warm the fuel before it gets that far. The filters may be heated with power from the 12-volt system, or warmed with engine coolant if the engine is running. If your unit has a Webasto type heating system, it can be used to preheat the engine and filters before you try to start the engine on a cold day. Some drivers have found that cycling the glow plugs several times also helps on cold mornings. If you are a trip back from the sunny south and have been running on #2 fuel, be sure to fill up with winterized #1 diesel (the more refined fuel that has less parafin wax) before getting too far north. On a cold morning, we have often seen a tractor-trailer stalled in the driving lanes, waiting to be towed into a warm garage to allow the wax clogging the fuel filter to liquify.

Sludge tends to be a problem that is mostly limited to older diesels that have accumulated many miles. It¡¯s a ¡°blackish¡± substance similar to algae¡ªthough it¡¯s not living. Sludge builds up in the fuel system over time. Basically, it¡¯s ¡°dirt¡± that settles to the bottom of the fuel tank. While it is generally harmless after it has settled at the bottom of the fuel tank, when biodiesel is added to the mix, the sludge can be loosened and suspended in the fuel, causing the fuel filter to clog more quickly. Biodiesel acts as a detergent and will eventually clean out most of the sludge that has built up in the fuel system.

Ethanol Considerations

Ethanol must be blended with gasoline. But ethanol is hydrosopic - it absorbs water. Gasoline doesn't. Therefore, ethanol cannot be shipped by regular petroleum pipelines. Instead, it must be segregated from other motor fuels and shipped by truck, rail car, or barge. Those shipping methods are far more expensive than pipelines.

Ethanol contains about 76,000 BTUs of energy per gallon, but producing that ethanol from corn and shipping it to the refinery takes about 98,000 BTUs. This is a negative gain for energy used. By comparison, a gallon of gasoline contains about 116,000 BTUs per gallon. But the total process of making and shipping that gallon of gas requires only around 22,000 BTUs.

By federal mandate, the USA must use 8 billion gallons of renewable fuels by the year 2012, up from an estimated 5 billion gallons this year. A target of 8 billion gallons of ethanol may sound like a lot, until you realize that America burned more than 134 billion gallons of gasoline last year. By 2012, those 8 billion gallons might reduce America's overall oil consumption by 0.5 percent.

For every gallon of alternative fuel that we burn, that is a gallon of petroleum fossil fuel that we do not have to take out of the ground or buy from a foreign country. While a gallon of ethanol-blended gas may cost the same as regular gasoline, it won't take you as far.

Since biodiesel is cleaner burning, emissions are greatly reduced. To put this in perspective, biodiesel reduces the carbon monoxide emissions by half. The Canadian government estimates that, if 35% of gasoline in Canada contained 10% ethanol, emissions would be reduced by 1.8 megatonnes per year (1.8 million tonnes), which is the equivalent of removing more than 400,000 vehicles from the road.

That certainly seems to be a strong argument in favour of the new biofuel blends, even if they may not be quite as convenient as traditional fuels.
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